Ultrafast AFM
Research Interests
2D materials
Thin film molecule samples
Defects
Motivation
Understanding the fundamental properties of nanomaterials has potential applications in areas including solar cell devices and molecular materials.
Ultrafast AFM
The Ultrafast AFM technique was first developed in our group by Schumacher et al. in 2017 by combining an ultrafast laser with non-contact AFM. When the laser impinges on the sample, it generates a photoinduced sample response, which is then detected as a force by the AFM tip. The temporal resolution of this technique is afforded by the ultrafast laser, and reaches the femtosecond regime. The spatial resolution is afforded by the sharpness of the AFM probe, and reaches the nanometer regime. This unique combination of spatial and temporal resolution will allow us to characterize local recombination rates and carrier decay times in photovoltaic materials.
Ultra-High Vacuum System
The centerpiece of the atomic manipulation facility is a custom built JEOL JSPM-4500A ultrahigh vacuum, low temperature, surface science system. This instrument consists of several standard surface science tools, along with an AFM (atomic force microscope), an STM (scanning tunneling microscope) and an FE-SEM (field emission-secondary electron microscope) which allows the AFM or STM tip to be accurately positioned over regions of interest on a sample.
We have recently modified the JEOL system for ultrafast AFM by incorporating:
Two ultrafast FemptoFiber Pro ultrafast lasers (one is centered in the near-infrared at 780 nm with 100 fs pulses, and the other is a tunable visible laser with 400 fs pulses).
Zurich Instruments UHF Lock-in amplifier.
A piezo-controlled optical mirror in UHV to steer the laser beam onto the sample.
General
Three chamber ultrahigh vacuum system: quick load lock chamber, specimen treatment chamber, analysis chamber
Base pressure in treatment and analysis chambers less than 10e-8 Pa
Specimen Treatment Chamber
LEED/Auger spectrometer
Four-source e-beam evaporator for the deposition of metals
Three source evaporator for the deposition of organic molecules
Quartz crystal deposition monitor for determining thickness of evaporated films
Ion gun
Specimen cleaving device
In situ mask system for depositing macroscopic electrode patterns (designed in-house)
Analysis Chamber
AFM: frequency modulated atomic force microscopy (NC-AFM), contact mode, tapping mode, magnetic force microscopy, electric force microscopy, Kelvin force microscopy, friction force microscopy, phase detection, current image
STM: I-V, S-V, I-S, CITS
Field emission SEM, designed for observing tip and/or sample on SPM stage.
Imaging can be performed at temperatures ranging from 30 K to 800 K
Nanonis SPM Control System with dual PLL
Ultrafast AFM
People
Group Members
Megan Cowie (PhD student)
Josephine Spiegelberg (Masters student)
Former Group Members
Rikke Plougmann (PhD student)
Andreas Spielhofer (PhD graduate '19)
Rasa Rejali (Master graduate)
Zeno Schumacher (PhD graduate)
Antoni Tekiel (PhD graduate '13)
Jessica Topple (PhD graduate '12)
Shawn Fostner (PhD graduate '10)
Sarah Burke (PhD graduate '09)
Jeffrey Mativetsky (PhD graduate '06)
Collaborators
David Cooke (McGill University)
Carlos Silva (Université de Montréal)
Hong Guo (McGill University)
Regina Hoffmann (University of Karlsruhe, Germany)
Yoichi Miyahara (McGill University)
Recent publications
Z. Schumacher, Y. Miyahara, A. Spielhofer, and P. Grutter: "Measurement of Surface Photovoltage by Atomic Force Microscopy under Pulsed Illumination" , Phys. Rev. Applied 5, 044018 (2016)
A. Tekiel, Y. Miyahara, J. M. Topple, and P. Grütter: "Room-Temperature Single-Electron Charging Detected by Electrostatic Force Microscopy", ACS Nano 7, 4683–4690 (2013)
A. Tekiel, S. Fostner, J. M. Topple, Y. Miyahara, and P. Grütter: "Reactive growth of MgO overlayers on Fe(001) surfaces studied by low-energy electron diffraction and atomic force microscopy", Appl. Surf. Sci. 273, 247-252 (2013)
A. Tekiel, J. M. Topple, Y. Miyahara, and P. Grütter, "Layer-by-layer growth of sodium chloride overlayers on the Fe(001)-p(1x1)O surface", Nanotechnology 23, 505602 (2012)
D. Stoffler, F. Fostner, P. Grütter, R. Hoffmann-Vogel, "Scanning probe microscopy imaging of metallic nanocontacts", Phys. Rev. B 85, 033404 (2012)
S. Fostner, A. Tekiel, J.M. Topple, Y. Miyahara and P. Grütter, "Field deposition from metallic tips onto insulating substrates", Nanotechnology 22, 465301 (2011)
J. Topple, S.A. Burke, W. Ji, S. Fostner, A. Tekiel, P. Grutter, "Tailoring the Morphology and Dewetting of an Organic Thin Film", J. Phys. Chem. C 115(1), 217 (2011)